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Chain scission. Branching. Gamma radiation. Polypropylene. CSDF. a b s t r a c t. The degradation of high molecular weight isotactic polypropylene (iPP) subjected to gamma rays irradiation up to 100 kGy in inert atmosphere was analyzed. The investigation relied upon complex viscosity, elastic modulus, gel fraction,
Radiation Effects on Polymeric. Systems. Crosslinking and Scission. • Both crosslinking and scission occur on irradiation of polymers; however, their relative importance varies from polymer to polymer
Molecular Level Chain Scission Mechanisms of Epoxy and. Urethane Polymeric Films Exposed to UV/H2O. Multidimensional Spectroscopic Studies. Heung Kim and Marek W. Urban*. The University of Southern Mississippi, School of Polymers and High Performance Materials,. Department of Polymer Science, Shelby F.
7 Nov 2006 We report that previous polymer chain scission experiments in strong flows, long analyzed according to accepted laminar flow scission theories, were in fact affected by turbulence. We reconcile existing anomalies between theory and experiment with the hypothesis that the local stress at the Kolmogorov
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Abstract. Relations between the soluble fraction and the number of effective chains between crosslinks in a three-dimensional network undergoing a scission reaction have been derived. Three limiting cases have been considered: (a) random scission in the chains, (b) scission in the chains directed by the crosslinks, and
‘Tim Winton is the real thing: a writer who can photograph a thought and pluck out the beat of a soul on a washing line’ Scotland on Sunday. In this, Tim Winton’s first collection of short stories, the world he paints is often harsh and disturbing, inhabited by isolated
Acknowledgment. This work was supported in part by a grant from the National Science Foundation. We are in- debted to Professors J. L. Schrag and R. B. Bird for valu- able discussions, to Professor M. Kurata for the polymer samples, and to Mr. F. H. M. Nestler and Miss Hsin Huang for help with calculations. J.W.M.N. is
We defined the optimal shape which fissioning nuclei attain just before the scission and calculated the deformation energy as function of the mass asymmetry and elongation at the scission point. The calculated deformation energy is used in quasi-static approximation for estimation of the mass distribution of fission
devised to circumvent polymer degradation due to the upstream contraction and thereby conduct degradation experiments in which only the turbulent flow in the pipe is responsible for chain scission. In this case, the scission-scaling relationship for PEO is ?w. Mw. ?3.20±0.28. Here Mw is the degraded weight-average molar
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