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Matter exists as gas, liquid, and solid phases, as has been recognized by classical science. The molecules that are situated at the interfaces (e.g., between gas–liquid, gas–solid, liquid–solid, liquid1–liquid2, solid1–solid2) are known to behave differently from those in the bulk phase [1–17]. It is also well-known that the
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This book has been written to fill a gap in the literature by offering a standard and overall coverage of colloid and surface chemistry intermediate between the brief accounts found in most textbooks of physical chemistry and the comprehensive accounts found in special- ised treatises on colloid and/or surface chemistry.
The position of surface chemistry in relation to biology has been reviewed by Rideal' and Alexander5. This review deals with some aspects of surface and colloid chemistry whose further development should be of application in pharmacy. SURFACE TENSION AND SURFACE ACTIVITY. The surface tension of a liquid can
When matter is very finely divided, its surface is enormously increased and its properties may change appreciably. The increased fraction of molecules in or near the surface and the asymmetric distribution of matter about them impart new properties to the surface. Surface Chemistry deals with these effects – particularly
Destabilisation of a colloid to form macroscopic lumps • Can be by: – Heating: forces particles together and/or changes nature of stabiliser. – Stirring: forces particles together. – Adding salt (electrolyte): shrinks double layer and/or neutralises inherent charge (e.g. on clay). – Changing pH: can flatten/desorb electrosteric
The face of colloid and surface chemistry has changed dramatically in the 10 years since the last edition of this book appeared in print. Advances in instrumentation now make it possible for us to “see"- and, indeed, to manipulate-individual atoms on a surface. Molecular engi- neering of polymers, surfactants, and particles is
tion'' of surface and colloid science in the overall context of chemistry, physics, biology, medicine, and other disciplines, this second edition is designed more in the style of a textbook. A number of errors and omissions pointed out by reviewers and readers have (hopefully) been corrected. Several important topics that were
The online version of Introduction to Colloid and Surface Chemistry by Duncan Shaw on ScienceDirect.com, the world's leading platform for high quality peer-reviewed full-text books.
A colloidal system represents a multiphase (heterogeneous) system, in which at least one of the phases exists in the form of very small particles: typically smaller than 1 mm but still much larger than the molecules. Such particles are related to phenomena like Brownian motion, diffusion, and osmosis. The terms
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