August
Friday 13 February 2009 photo 1/1
|
Friday 13 February 2009 photo 1/1
|
|
For Informational Purposes Only. The authors & distributors do notadvocate the use of illegal drugs and assume no liability for the use ormisuse of this information . The procedures described are dangerous and shouldnot be attempted by persons inexperienced in Organic Laboratory techniques.
This formula is exemplified for MDA (3,4-Methylenedioxyphenylisopropylamine);substituting N-methyl formamide results in MDMA or N-methyl MDA (Ecstacy).
To a cooled mixture of 34 g 30% H2O2 and 150 g formic acid, add dropwisea solution of 32.4 g (0.2M) isosafrole in 120 ml acetone, (keep temperaturebelow 30 degrees) Let stand twelve hours and evacuate in vacuum. Add 60ml methanol and 369 g 15% sulfuric acid to the residue and heat on a waterbath three hours. Cool, extract with ether or benzene and evaporate in vacuumthe extract to give 20 g 3,4,-methylenedioxybenzylmethyl ketone.
Add 23 g of above ketone to 65 g formamide and heat at 190 degrees forfive hours. Cool, add 100 ml H2o2, extract with benzene and evaporate invacuum the extract. Add 8 ml methanol and 57 ml 15% HCL to residue, heaton water bath two hours and evaporate in vacuum (or basify with KOH and extractthe oil with benzene and dry, evaporate in vacuum) to get 11.7 g MDA.
The above occurs as a yellowish brown oil; this is active orally, butsomewhat inconvenient; to convert to powder (salt) form, reflux in Hydrochloricacid and evaporate.
Safrole, an allyl benzene, occurs naturally in oil of sassafras, about70%. Can be extracted with simple distillation. It is con- verted to isosafrole(a propenyl benzene) by adding equal weight of KOH flakes and absolute ethanoland heating on steam bath or refluxing for 24 hours; dried and evaporatedin vacuum or added with two time its volume in water and extracted with etheror methylene chloride and dried, evaporated in vacuum. Hexane is used forrecrystalization.
Formamide and N-methyl formamide are closely watched by the DEA. Manypeople have been busted by small suppliers where it was easy to get; thoseare "sting" operations that tail the buyer home.
7.0 Ecstasy (Metod 2)40.4 g 3,4-methylenedioxybensaldehyde and 16 g nitroethane in 150 ml glacialacetic acid and 15 g ammoniumacetate. Reflux 1.5 hours; cool, filter andrecrystallize from acetic acid or methanol to get the nitropropene.
Reduce the nitropropene as follows:
Suspend 0.2 M of the nitropropene and Zn-Hg from 200 g Zn and 20 g HgCl2in 2 L ethanol and add with vigorous stirring portions of concentrated HCluntil the yellow colour disappears. Continue stirring one half hour, filter,evaporate in vacuum to get about 0.14 M of 3,4-methylenedioxyamphetamine.
If you want the hydrochloride salt of the amine, dissolve it in etherand mix with one third its volume of absolute ethanol. Slowly and with continousswirling and ice cooling add concentrated hydrochloric acid until no morecrystals precipitates. Cool to 0 and filter to get the amine hydrochloride.
Regarding the reduction, I would rather use an lithiumaluminiumhydridereduction process instead of Zn-Hg since Hg salts are very poisonous. Itwould decrease the risk of dangerous impurities in the final product.
OBS OBS!
Jag har ingenting med formlerna att göra, det var vissa som ville se ENDAST!
Visa toppen
Show footer