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Predict the sign of ?S for physical and chemical processes. ? State the third law of thermodynamics. ? Calculate standard entropy changes for a system from standard molar entropies. ? Calculate entropy changes in the surroundings for isothermal processes. ? Calculate the Gibbs free energy from the enthalpy change and
the system under observation is an ideal gas thus the internal energy of the system is dependent only on the inetic energy of the gas and therefore is only a function of temperature. U v T. Since internal energy depends only on temperature thus, it is a state function. 6. CHEMICAL THERMODYNAMICS AND ENERGETICS
CHEMICAL ENERGETICS. ENTHALPY & ENTHALPY CHANGES.. The total chemical energy of a substance is called its enthalpy (heat content). It is an indication of the energetic stability and not kinetic stability. Chemical energy consists of kinetic energy and potential energy. The potential energy, due to
7 In an experiment to calculate the enthalpy change of combustion of a fuel, 1.5 g (0.0326 mol) of the fuel was used to heat 200 g of water. The temperature of the water rose from 25 °C to 55 °C. The specific heat capacity of water is 4.18 J g-1 K-1. There is significant heat loss in this experiment. Therefore, the experimental
Chemical reactions involve the breaking and making of bonds. 0. Breaking bonds requires energy ,whereas energy is given out when new bonds are formed. 0. Energy: the ability to do work (= move a force through a distance) e.g. heat, light, sound, electricity, chemical energy. Energy (J) = force (N) x distance (m).
This document covers the basics of chemical thermodynamics, the First Law, and thermochemistry at a level appropriate for first-year college chemistry. It was last modified on 23 December 2003 . It can be downloaded from www.chem1.com/acad/pdf/energetics.pdf. A Web-based version is available at
26 Sep 2010 Chapter 14 – Energetics. Page 1. Chapter 14 – Energetics. Topics 05 and 15 from the IB HL Chemistry Curriculum. 5.1 Exothermic and endothermic reactions (1 Hour). Assessment Statement. Obj Teacher's Notes. 5.1.1. Define the terms exothermic reaction, endothermic reaction and standard enthalpy.
Energetics Questions: Question 1: Enthalpy Changes 1. Looking at the graphs and equations shown below, identify which graph belongs to which reaction. State which process is exothermic and which is endothermic. Reaction 1 has a ?rH value of +126 kJ mol. -1 and reaction 2 has a. ?rH value of -107 kJ mol. -1.
carbohydrates such as glucose in respiration. 1.4 Energetics. Definition: Enthalpy change is the amount of heat energy taken in or given out during any change in a system provided the pressure is constant. . independent of the route by which the chemical change takes place. Hess's law is a version of the first.
CHEMICAL ENERGETICS. CONTENTS. 2. Some Experiments. 3. System And Surroundings. 4. System And Surroundings. 5. System And Surroundings. 6. Kinetics And Thermodynamics. 7. Energy. 8. Energy And Force. 9. Kinetic And Potential Energy. 10. Kinetic And Potential And Thermal Energy. 11. Chemical Energy. 11.
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